ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Total synthesis of HM-1 and HM-2, aromatic sesquiterpenes isolated from the phytopathogenic fungus $\mathit{Helicobasidium{\:}mompa}$. Structure revision of HM-2

Srikrishna, A and Ravikumar, PC (2005) Total synthesis of HM-1 and HM-2, aromatic sesquiterpenes isolated from the phytopathogenic fungus $\mathit{Helicobasidium{\:}mompa}$. Structure revision of HM-2. In: Tetrahedron Letters, 46 (36). pp. 6105-6109.

[img] PDF
sdarticle.pdf - Published Version
Restricted to Registered users only

Download (134Kb) | Request a copy
Official URL: http://www.sciencedirect.com/science?_ob=ArticleUR...

Abstract

The structure assigned to the sesquiterpene HM-2 was found to be incorrect by total synthesis. A ring-closing metathesis based strategy was developed for the total synthesis of the aromatic sesquiterpene HM-1, which on functional group transformation established the structure of HM-2 as 23, a cuparene derivative. (c) 2005 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier.
Keywords: HM-1 to 4;Structure revision;Herbertenoids;Cuparenoids;RCM.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 04 Feb 2010 10:51
Last Modified: 19 Sep 2010 04:56
URI: http://eprints.iisc.ernet.in/id/eprint/17407

Actions (login required)

View Item View Item