Sureshkumar, Devarajulu and Maity, Susama and Chandrasekaran, Srinivasan (2006) Regio- and Stereoselective Synthesis of Aziridino Epoxides from Cyclic Dienes. In: Journal Of Organic Chemistry, 71 (4). pp. 1653-1657.
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Two different routes for the regio- and stereoslective synthesis of aziridino epoxides from cyclic dienes have been explored. The first strategy involves regiospecific aziridination of cyclic diene derivatives and subsequent epoxidation with m-CPBA to yield cis-aziridino epoxides as major products. The second strategy utilizes regiospecific epoxidation of cyclic diene derivatives followed by Sharpless aziridination to provide exclusively trans-aziridino epoxides. Synthesis of both enantionters of cis-aziridino epoxides from (R)-(-)- and (S)-(+)-carvones are also reported.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to American Chemical Society.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||08 Apr 2009 05:49|
|Last Modified:||19 Sep 2010 04:58|
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