Choudhury, Amitava and Natarajan, Srinivasan and Rao, CNR (1999) An open-framework iron phosphate with large voids, exhibiting spin-crossover. In: Chemical Communications (14). pp. 1305-1306.
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Official URL: http://www.rsc.org/publishing/journals/CC/article....
Abstract
A novel iron phosphate, [(C4N3H16)(C4N3H15)](5+)-[Fe5F4(H2PO4)(HPO4)(3)(PO4)(3)](5-). H2O, consisting of a Fe-O/F-Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe, P) and to exhibit a gradual low- to high-spin transformation.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Royal Soc Chemistry. |
| Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
| Date Deposited: | 10 Feb 2010 07:23 |
| Last Modified: | 19 Sep 2010 04:59 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/17966 |
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