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A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of ${\beta}$-microbiotene, microbiotol and cyclocuparanol

Srikrishna, Adusumilli and Nagamani, Anitha S (1999) A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of ${\beta}$-microbiotene, microbiotol and cyclocuparanol. In: Perkin Transactions 1 (23). pp. 3393-3394.

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Abstract

Employing an epoxide rearrangement based ring contraction reaction, a short and efficient regioselective approach to the C-6 to C-19 segment of the toluquinol substituted diterpenes bifurcaranes, and its extension to a formal total synthesis of the sesquiterpenes (+/-)-beta-microbiotene, (+/-)-microbiotol and (+/-)-cyclocuparanol are described.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to The Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 10 Feb 2010 07:19
Last Modified: 19 Sep 2010 04:59
URI: http://eprints.iisc.ernet.in/id/eprint/18009

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