ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

An intramolecular rhodium carbenoid C-H insertion approach to chiral isotwistanes. Synthesis of (-)-neopupukean-4,10-dione and (-)-neopupukean-10-one

Srikrishna, A and Gharpure, Santosh J (1998) An intramolecular rhodium carbenoid C-H insertion approach to chiral isotwistanes. Synthesis of (-)-neopupukean-4,10-dione and (-)-neopupukean-10-one. In: Chemical Communication (15). pp. 1589-1590.

[img] PDF
An_intramolecular_rhodium.pdf - Published Version
Restricted to Registered users only

Download (62Kb) | Request a copy
Official URL: http://www.rsc.org/Publishing/Journals/CC/article....

Abstract

The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Michael reaction and a regioselective intramolecular rhodium carbenoid C-H insertion reaction as key steps, is described.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 26 Aug 2009 18:06
Last Modified: 19 Sep 2010 04:59
URI: http://eprints.iisc.ernet.in/id/eprint/18025

Actions (login required)

View Item View Item