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(5S)-1,4-Bis{[(1E)-4-methylbenzylidene]-amino}-5-(thien-2-yl)pyrrolidin-2-one

Chopra, Deepak and Venugopala, KN and Rao, GK (2007) (5S)-1,4-Bis{[(1E)-4-methylbenzylidene]-amino}-5-(thien-2-yl)pyrrolidin-2-one. In: Acta Crystallographica Section E Structure Reports Online, 63 (6). 2840-2840; Sup. 1-10.

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Official URL: http://journals.iucr.org/e/issues/2007/06/00/sj230...

Abstract

In the crystal structure of the title compound, C25H24SN4O2, the pyrrole ring adopts an envelope conformation. Each of the 4-methylbenzylidene units is planar and they make angles of 12.26 (8) and 85.46 (10)degrees with the four coplanar atoms of the pyrrole ring. The thiophene ring makes an angle of 75.06 (9)degrees with this plane. The crystal structure is stabilized by intermolecular N - H...O and C - H...O hydrogen bonds.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to International Union of Crystallography.
Keywords: single-crystal X-ray study; T = 290 K; mean sigma(C–C) = 0.004 A°;R factor = 0.062; wR factor = 0.140; data-to-parameter ratio = 15.5.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 22 Jan 2009 06:12
Last Modified: 19 Sep 2010 04:59
URI: http://eprints.iisc.ernet.in/id/eprint/18071

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