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Biomimetic aerobic polymerization of vinyl monomers

Jayaseharan, J and Kishore, K (1998) Biomimetic aerobic polymerization of vinyl monomers. In: Journal of Americal Chemical Society, 120 (4). pp. 825-826.

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Official URL: http://pubs.acs.org/doi/pdf/10.1021/ja971335s

Abstract

This is the first report of biomimetic aerobic polymerization of vinyl monomers, which has been achieved under mild conditions. When a homogeneous solution of a vinyl monomer containing a reversible oxygen carrier, namely 5,10,15,20 tetraphenyl-21H, 23H-porphinecobalt(II) pyridine complex [CoTPP(Py)], is exposed to air at room temperature, an alternating copolyperoxide is obtained (eq 1).

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 26 Feb 2009 05:21
Last Modified: 19 Sep 2010 05:00
URI: http://eprints.iisc.ernet.in/id/eprint/18154

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