Jayaseharan, J and Kishore, K (1998) Biomimetic aerobic polymerization of vinyl monomers. In: Journal of Americal Chemical Society, 120 (4). pp. 825-826.
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This is the first report of biomimetic aerobic polymerization of vinyl monomers, which has been achieved under mild conditions. When a homogeneous solution of a vinyl monomer containing a reversible oxygen carrier, namely 5,10,15,20 tetraphenyl-21H, 23H-porphinecobalt(II) pyridine complex [CoTPP(Py)], is exposed to air at room temperature, an alternating copolyperoxide is obtained (eq 1).
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to American Chemical Society.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||26 Feb 2009 05:21|
|Last Modified:||19 Sep 2010 05:00|
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