Two-Dimensional Solid State NMR and Separation of 7Li Quadrupolar Interactions in Paramagnetic Compounds

Ganapathy, S and Rajamohanan, PR and Ganguly, P (2000) Two-Dimensional Solid State NMR and Separation of 7Li Quadrupolar Interactions in Paramagnetic Compounds. In: Journal of Physical Chemistry A, 104 (10). pp. 2007-2012.

PDF Two-Dimensional.pdf - Published Version Restricted to Registered users only Download (127Kb) | Request a copy

Abstract

Ln layered paramagnetic compounds, such as La2Li0.5Ni0.5O4 with a perovskite structure, the Li-7 NMR spectrum is broadened by anisotropic quadrupolar as well as paramagnetic dipolar interactions. We have used a two-dimensional spin echo (SE) experiment to separate the quadrupolar interaction and obtain a clean quadrupolar spectrum along the wi dimension. This is demonstrated in La2Li0.5B0.5O4 (B = Cu, Ni), through 2D SE experiments conducted in static samples as well as those in spinning at the magic angle. A quadrupole coupling constant of 92 kHz is estimated from the Wi spectrum for paramagnetic La2Li0.5Ni0.5O4.

Item Type:	Journal Article
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Sophisticated Instruments Facility
Date Deposited:	20 Nov 2009 06:59
Last Modified:	19 Sep 2010 05:01
URI:	http://eprints.iisc.ernet.in/id/eprint/18313

Actions (login required)

View Item