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Conserved hydrogen bonded tartrate frameworks: Inclusion of amines and implications for second harmonic generation

Kadirvelraj, R and Bhattacharya, S and Guru Row, TN (1998) Conserved hydrogen bonded tartrate frameworks: Inclusion of amines and implications for second harmonic generation. In: Journal of Inclusion Phenomena and Macrocyclic Chemistry, 30 (4). pp. 321-331.

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Abstract

A series of anilinium cations with various functional groups as substituents has been chosen to form salts with L-tartaric acid and D-dibenzoyl tartaric acid. The salts show second harmonic generation activities comparable to urea. The tartrate frameworks provide conformationally rigid hydrogen bonded frameworks for the incorporation of these cations. The SHG activity of these salts appear to depend upon the type of framework provided by the tartrate anions, which in turn decides the orientation of the cations.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Springer.
Keywords: supramolecular chemistry;hydrogen bonding;second harmonic generation;anionic framework.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Chemical Sciences > Organic Chemistry
Date Deposited: 18 May 2009 04:46
Last Modified: 19 Sep 2010 05:01
URI: http://eprints.iisc.ernet.in/id/eprint/18314

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