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An unusual reaction of cyclic enol ethers with titanium(III) tetrahydroborate

Ravikumar, KS and Chandrasekaran, S (1997) An unusual reaction of cyclic enol ethers with titanium(III) tetrahydroborate. In: Tetrahedron, 53 (8). pp. 2973-2978.

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Abstract

Titanium(III) Tetrahydroborate formed in situ from titanium tetrachloride and benzyltrieihylammonium retrahydroborate (1:4) readily reacts with cyclic enol ethers in dichloromethane at -20 degrees C to give the corresponding acyclic diols in high yields after simple aqueous work-up.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 08 Feb 2010 06:30
Last Modified: 19 Sep 2010 05:01
URI: http://eprints.iisc.ernet.in/id/eprint/18397

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