Suresh Kumar, EVK and Singh, Jai D and Singh, Harkesh B and Das, Kalyan and Yakhmic, Jatinder V and Butcher, Ray J (1998) Dithiaheterocycle-annelated tetrathiafulvalene pi-donors: a structure-property correlation study. In: The Journal of Chemical society Parkin Trnansactions 1 (11). pp. 1769-1778.
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Single-crystal X-ray structures of BEDT-TTF analogues 3, 6, 7 and 7a along with the preparation of a range of new cation-radical salts derived from these x-electron donors are reported. Physical properties (i.e. colour, cyclic voltammetry data and solid-state conductivities of the derived cation-radical salts) of the donors are discussed in terms of their crystal and molecular structures. The synthesis of compound 7 has been re-investigated. An efficient synthesis of both isomers 7 and 7a along with the other related TTF derivatives is presented. The crystal structure of the precursor thione 10 is also described.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Royal Society Chemistry.|
|Department/Centre:||Division of Biological Sciences > Molecular Biophysics Unit|
|Date Deposited:||18 May 2009 09:40|
|Last Modified:||19 Sep 2010 05:01|
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