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Volume-Demanding Cis-Trans Isomerization of 1,2-Diaryl Olefins in the Solid State

Natarajan, Arunkumar and Mague, Joel T and Venkatesan, K and Arai, T and Ramamurthy, V (2006) Volume-Demanding Cis-Trans Isomerization of 1,2-Diaryl Olefins in the Solid State. In: Journal Of Organic Chemistry, 71 (3). pp. 1055-1059.

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Abstract

Volume-demanding cis-trans photoisomerization of the aromatic substituted alkenes 1-3 in the solid state at roorn temperature and at 50 degrees C is presented. Alkene 3 did not undergo the cis-trans isornerization in the solid state either at room temperature or at 50 degrees C. The importance of the presence of void space near the reaction center to facilitate the large volume change during cis-trans photoisomerization is discussed.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 13 Apr 2009 09:40
Last Modified: 19 Sep 2010 05:02
URI: http://eprints.iisc.ernet.in/id/eprint/18473

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