ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Total synthesis of (G)-herbertenediol

Srikrishna, A and Satyanarayana, G (2006) Total synthesis of (G)-herbertenediol. In: Tetrahedron, 62 (12). pp. 2892-2900.

[img] PDF
Total_synthesis.pdf - Published Version
Restricted to Registered users only

Download (235Kb) | Request a copy
Official URL: http://www.sciencedirect.com/science?_ob=MImg&_ima...

Abstract

A formal total synthesis of the sesquiterpene (+/-)-herbertenediol and its dimers mastigophorenes A-D has been accomplished, starting from vanillin via 2,3-dimethoxy-5-methylbenzaldehyde. A combination of Claisen rearrangement and ring-closing metathesis reactions were employed for the generation of the two vicinal quaternary carbons on a cyclopentane ring

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsavier.
Keywords: Herbertanes;Mastigophorenes;RCM reaction;Claisen rearrangement;Vicinal quaternary carbon atoms.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 13 Apr 2009 06:41
Last Modified: 19 Sep 2010 05:02
URI: http://eprints.iisc.ernet.in/id/eprint/18475

Actions (login required)

View Item View Item