Prasad, Kavirayani R and Chandrakumar, Appayee (2006) Nucleophilic addition reactions of 1,4-diketones derived from tartaric acid: Synthesis of TADDOL analogues. In: Synthesis-Stuttgart (13). pp. 2159-2166.
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Official URL: http://www.thieme-connect.de/DOI/DOI?10.1055/s-200...
Abstract
A systematic investigation of the reduction and Grignard reagents addition to 1,4-diketones derived from tartaric acid was carried out. It was found that the reduction proceeded with high selectivity using K-Selectride as the reducing agent; while Grignard reagent addition was highly dependent on structure of the dione as well as on the Grignard reagent. The resultant 1,4-diols represent a series of novel TADDOL analogues.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Georg Thieme Verlag Kg. |
| Keywords: | asymmetric synthesis;TADDOL;stereoselective addition. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 06 Apr 2009 04:51 |
| Last Modified: | 06 Apr 2009 04:51 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/18586 |
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