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Chiral synthons from carvone .24. Photochemical rearrangements of chiral bicyclo[2.2.2]oct-5-en-2-ones

Srikrishna, A and Danieldoss, S (1997) Chiral synthons from carvone .24. Photochemical rearrangements of chiral bicyclo[2.2.2]oct-5-en-2-ones. In: Synthetic Communications, 27 (4). pp. 655-661.

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Abstract

Photochemical oxadi-pi-methane rearrangement (1,2-acyl shift) of the chiral bicyclo[2.2.2]oct-5-en-2-ones 2 and 3 furnishes the tricyclic ketones 5 and 6, whereas the 1,3-acyl shift generates the cyclobutanones 7 and 8 respectively.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 29 May 2009 09:30
Last Modified: 19 Sep 2010 05:24
URI: http://eprints.iisc.ernet.in/id/eprint/18692

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