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Enantiodivergent synthesis of both antipodes of hydroxy-exo-brevicomin from L-(D)-tartaric acid

Prasad, Kavirayani R and Anbarasan, Pazhamalai (2006) Enantiodivergent synthesis of both antipodes of hydroxy-exo-brevicomin from L-(D)-tartaric acid. In: Tetrahedron, 62 (35). pp. 8303-8308.

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Abstract

An enantiodivergent approach to both antipodes of hydroxy-exo-brevicomin was achieved from a common chiral precursor L-(+)-tartaric acid. The strategy utilizes the elaboration of a keto-Weinreb amide and successive stereoselective reductions.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsavier.
Keywords: Stereoselective reduction; L-(+)-Tartaric acid;Hydroxy-exo-brevicomin;6,8-Dioxabicyclo[3.2.1]octane.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 23 Mar 2009 09:04
Last Modified: 19 Sep 2010 05:25
URI: http://eprints.iisc.ernet.in/id/eprint/18749

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