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Cyclopropane formation vs the homoallyl homoallyl radical rearrangement in 7-oxygen-substituted norborn-5-en-2-yl radicals

Srikrishna, A and Viswajanani, R and Reddy, T Jagadeeswar and Vijaykumar, D and Kumar, P Praveen (1997) Cyclopropane formation vs the homoallyl homoallyl radical rearrangement in 7-oxygen-substituted norborn-5-en-2-yl radicals. In: Journal of Organic Chemistry, 62 (15). pp. 5232-5234.

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Official URL: http://pubs.acs.org/doi/pdf/10.1021/jo970246v

Abstract

The homoallyl-homoallyl radical rearrangement via the cyclopropylcarbinyl radical (eq 1) plays an important role in mechanistic organic chemistry.1 Although considerable amount of work was done from the point of view of its use as a radical clock, isolation of products resulting from the trapping of the intermediate cyclopropylmethyl radical is not that common.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 12 Mar 2009 09:43
Last Modified: 19 Sep 2010 05:25
URI: http://eprints.iisc.ernet.in/id/eprint/18787

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