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Enantioselective First Total Syntheses of 2-(Formylamino)trachyopsane and ent-2-(Isocyano)trachyopsane via a Biomimetic Approach

Srikrishna, A and Ravi, G and Subbaiah, Venkata DRC (2009) Enantioselective First Total Syntheses of 2-(Formylamino)trachyopsane and ent-2-(Isocyano)trachyopsane via a Biomimetic Approach. In: Synlett (1). pp. 32-34.

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Official URL: https://www.thieme-connect.de/DOI/DOI?10.1055/s-00...

Abstract

A biomimetic rearrangement of an isotwistane to a tricyclo[4.3.1.0(3,8)]decane has been employed as the key step for the enantioselective first total syntheses of the marine sesquiterpenes 2-(formylamino)trachyopsane and ent-2-(isocyano)trachyopsanes ascertaining the biogenetic relationship between the marine sesquiterpenes neopupukeananes and trachyopsanes.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Georg Thieme Verlag Stuttgart.
Keywords: natural products; marine sesquiterpenes; enantioselective synthesis; biomimetic synthesis; acid-catalysed rearrangement
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 11 Jun 2010 08:23
Last Modified: 19 Sep 2010 05:25
URI: http://eprints.iisc.ernet.in/id/eprint/18801

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