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Microwave-assisted solid-state synthesis of oxide ion conducting stabilized bismuth vanadate phases

Vaidhyanathan, B and Balaji, KN and Rao, KJ (1998) Microwave-assisted solid-state synthesis of oxide ion conducting stabilized bismuth vanadate phases. In: Chemistry of materials, 10 (11). pp. 3400-3404.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/cm980092f

Abstract

A microwave-assisted method for the preparation of substituted bismuth vanadates has been described. The method consists of starting with the respective oxides mixed in stoichiometric proportions and exposing the mixture to microwaves. Substitution takes place at the vanadium sites and it has been possible to prepare Ag+-, Mn4+-, Ga3+-, Y3+-, and Ce4+-substituted compounds with up to 10% substitution. Mn4+- and Ag+-substituted compounds are found to exhibit better oxygen ion conductivities than any reported so far in the literature.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 24 Dec 2009 07:15
Last Modified: 19 Sep 2010 05:26
URI: http://eprints.iisc.ernet.in/id/eprint/18948

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