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New paradigms in cycloaddition face-selectivities: remarkable effect of remote substituents in singlet oxygen addition to hexacyclo$[7.5.1.0^{1,6}.0^{6,13}.0^{8,12}.0^{10,14}]$pentadeca-2,4-diene system

Mehta, Goverdhan and Uma, R and Jagadeeshb, MN and Chandrasekhar, Jayaraman (1998) New paradigms in cycloaddition face-selectivities: remarkable effect of remote substituents in singlet oxygen addition to hexacyclo$[7.5.1.0^{1,6}.0^{6,13}.0^{8,12}.0^{10,14}]$pentadeca-2,4-diene system. In: Chemical Communication (17). pp. 1813-1814.

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Abstract

Different modes of direct through-space interactions between remote substituents and an approaching reagent are indicated as important additional controlling factors of face selectivity in singlet oxygen cycloaddition to facially differentiated cyclohexa-1,3-dienes.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 16 Nov 2009 06:17
Last Modified: 19 Sep 2010 05:26
URI: http://eprints.iisc.ernet.in/id/eprint/18992

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