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Proton and carbon-13 NMR studies of conformational preferences in N-(2-pyridinyl)-2-pyridinecarboxamides

Singha, Netai C and Sathyanarayana, DN (1998) Proton and carbon-13 NMR studies of conformational preferences in N-(2-pyridinyl)-2-pyridinecarboxamides. In: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 54 (08). pp. 1059-1065.

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Abstract

The H-1 and C-13 NMR spectra, molecular conformation and intermolecular association of N-(2-pyridinyl)-2-pyridinecarboxamides and 2-pyridinecarboxamide are discussed. The H-1 NMR spectra have been analyzed with the aid of COSY spectra and the C-13 spectra with the aid of HETCOR, proton coupled spectra and C-13-H-1 coupling constants. In concentrated CDCl3 solution, N-(2-pyridinyl)-2-pyridinecarboxamides dimerise by intermolecular association.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: NMR spectroscopy;COSY;HETCOR;Conformation;N-(2-pyridinyl)-2-pyridine carboxamides.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 21 Dec 2009 11:11
Last Modified: 19 Sep 2010 05:26
URI: http://eprints.iisc.ernet.in/id/eprint/19104

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