Kanakamma, Puthuparampil P and Mani, Neelakandha S and Maitra, Uday and Nair, Vijay (1995) Chiral Crown-Ethers Incorporating D-Glucose. In: Journal Of The Chemical Society-Perkin Transactions, 1 (18). pp. 2339-2344.
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A novel class of crown ether derivatives incorporating D-glucose and poly(ethylene glycol) units has been synthesized from allyl alpha-D-glucopyranoside by a simple and efficient strategy. The complexing properties of these compounds with alkali metal cations and ammonium ion have been evaluated by Cram's picrate method. Catalytic activity of macrocycle 2 in asymmetric Michael addition reaction was also studied. The average cavity size of these macrocycles was determined by the application of the MMX programme.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Royal Society of Chemistry.|
|Date Deposited:||21 Feb 2010 09:44|
|Last Modified:||19 Sep 2010 05:27|
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