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Chiral Crown-Ethers Incorporating D-Glucose

Kanakamma, Puthuparampil P and Mani, Neelakandha S and Maitra, Uday and Nair, Vijay (1995) Chiral Crown-Ethers Incorporating D-Glucose. In: Journal Of The Chemical Society-Perkin Transactions, 1 (18). pp. 2339-2344.

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Abstract

A novel class of crown ether derivatives incorporating D-glucose and poly(ethylene glycol) units has been synthesized from allyl alpha-D-glucopyranoside by a simple and efficient strategy. The complexing properties of these compounds with alkali metal cations and ammonium ion have been evaluated by Cram's picrate method. Catalytic activity of macrocycle 2 in asymmetric Michael addition reaction was also studied. The average cavity size of these macrocycles was determined by the application of the MMX programme.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Keywords: Chemistry,Organic
Department/Centre: Others
Date Deposited: 21 Feb 2010 09:44
Last Modified: 19 Sep 2010 05:27
URI: http://eprints.iisc.ernet.in/id/eprint/19153

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