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Measurement of Partition Coefficients of Substituted Benzoic Acids between Two Immiscible Solvents by Hyper-Rayleigh Scattering

Ray, Paresh Chandra and Das, Puspendu Kumar (1996) Measurement of Partition Coefficients of Substituted Benzoic Acids between Two Immiscible Solvents by Hyper-Rayleigh Scattering. In: Journal of Physical Chemistry, 100 (39). pp. 15631-15633.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp9612137

Abstract

We demonstrate that the hyper-Rayleigh scattering technique can be employed to measure the partition coefficient (k(p)) of a solute in a mixture of two immiscible solvents. Specifically, partition coefficients of six substituted benzoic acids in water/toluene (1:1 v/v) and water/chloroform (1:1 v/v) systems have been measured. Our values compare well with the k(p) values measured earlier by other techniques, The advantages offered by this technique are also discussed.

Item Type: Editorials/Short Communications
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 12 Jan 2010 11:47
Last Modified: 19 Sep 2010 05:28
URI: http://eprints.iisc.ernet.in/id/eprint/19517

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