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Enantiospecific approach to the tricyclic core structure of tricycloillicinone, ialibinones, and takaneones via ring-closing metathesis reaction

Srikrishna, A and Beeraiah, B and Gowri, VS (2009) Enantiospecific approach to the tricyclic core structure of tricycloillicinone, ialibinones, and takaneones via ring-closing metathesis reaction. In: Tetrahedron, 65 (13). pp. 2649-2654.

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Abstract

Enantiospecific synthesis of the tricyclic core structure present in the biologically active natural products tricycloillicinone, ialibinones, and takaneones, starting from the readily available campholenaldehyde employing a transannular RCM reaction as the key step, has been accomplished.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Tricyclo[5.3.1.0]1(+)S]undecane;(S)-Campholenaldehyde; Enantiospecific synthesis; RCM reaction;Diquinanes;Illicinones.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 01 May 2009 03:23
Last Modified: 19 Sep 2010 05:29
URI: http://eprints.iisc.ernet.in/id/eprint/19667

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