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Structure of the Monosodium Salt of D-Glucose 6-Hydrogenphosphate

Narendra, N and Viswamitra, MA (1985) Structure of the Monosodium Salt of D-Glucose 6-Hydrogenphosphate. In: ACTA Crystallographica Section C-Crystal Structure Communications, 41 (Nov). pp. 1621-1624.

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Abstract

Na+.C6HI209 P-, Mr=282.1, monoclinic, e2~, a=5-762(1), b=7.163(2), c=12.313(1)A, fl= 99.97 (1) °, U= 500.5 A 3, Z= 2, D m = 1.86, D x = 1.87 Mg m -s, Cu Ka, 2 = 1.5418 A, /a = 3-3 mm -1, F(000) = 292, T= 300 K, final R for 922 observed reflections is 0-042. The phosphate ester bond, P-O(6), is 1.575 (5)A, slightly shorter than the P~O bond in monopotassium phosphoenolpyruvate [1.612 (6) A] [Hosur & Viswamitra (1981). Acta Cryst. B37, 839-843]. The pyranose sugar ring takes a 4C 1 chair conformation. The conformation about the exocyclic C(5)-C(6) bond is gauche-trans. The endocyclic C-O bonds in the glucose ring are nearly equal with C(5)-O(5) = 1.435 (8) and C(1)-O(5) = 1.436 (9) A. The sodium ion has seven near neighbours within a distance of 2.9 A. The crystal structure is stabilized by hydrogen bonds between the O atoms of symmetryrelated molecules.

Item Type: Journal Article
Additional Information: The copyright of this article belongs to International Union of Crystallography
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 09 Nov 2009 11:41
Last Modified: 19 Sep 2010 05:31
URI: http://eprints.iisc.ernet.in/id/eprint/20070

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