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XANES and EXAFS of copper compounds: Studies of copper carboxylates with metal-metal bonds and of the complex formed byPseudomonas aeruginosa

Sarode, PR and Sankar, G and Rao, CNR (1983) XANES and EXAFS of copper compounds: Studies of copper carboxylates with metal-metal bonds and of the complex formed byPseudomonas aeruginosa. In: Journal of Chemical Sciences, 92 (4-5). pp. 527-542.

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Abstract

X-ray absorpion near edge structure (xanes) of copper compounds with copper in 1+, 2+ and 3+ states has been studied. Extended x-ray absorption fine structure (exafs) has been employed to determine bond distances and coordination numbers in several model copper compounds. Employing bothxanes andexafs, the structure of the copper complex formed by the micro-organismPseudomonas aeruginosa has been shown to be square-planar with the Cu-O distance close to that in cupric glucuronates and cupric acetylacetonate.exafs has been shown to be useful for studying metal-metal bonds in copper carboxylates.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Springer.
Keywords: XANES - EXAFS - copper compounds - x-ray spectra
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 05 Nov 2009 10:20
Last Modified: 19 Sep 2010 05:31
URI: http://eprints.iisc.ernet.in/id/eprint/20143

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