Verneker, VR Pai and Santhanalakshmi, KN (1984) Initiation Reactions in Thermal Polymerization of Vinyl Monomers in the Molten State. In: Journal of Polymer Science: Polymer Chemistry Edition, 22 (11). pp. 3217-3224.
![[img]](http://eprints.iisc.ernet.in/style/images/fileicons/application_pdf.png) |
PDF
3fulltext.pdf - Published Version Restricted to Registered users only Download (408Kb) | Request a copy |
Official URL: http://www3.interscience.wiley.com/journal/1040556...
Abstract
Evidence of the initiation process during uncatalyzed thermal polymerization of vinyl monomers is presented. DSC studies reveal a prominent endothermic effect just before the polymerization exotherm, which is substantiated by the identification of the free radicals produced in the initiation by a quick quenching technique and subsequent detection by ESR at low temperatures.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to John Wiley and Sons. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 25 Aug 2009 10:28 |
| Last Modified: | 19 Sep 2010 05:31 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/20149 |
Actions (login required)
 |
View Item |
