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Photochemistry of dimethylthioketene dimers

Muthuramu, Kayambu and Ramamurthy, Vaidhyanathan (1980) Photochemistry of dimethylthioketene dimers. In: Journal of organic Chemistry, 45 (22). pp. 4532-4533.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo01310a063

Abstract

Thioketones and dithioesters, using 1,3-cyclobutanedithione and 3-mercapto-2,2,4-trimethyldithio-3-pentenoic acid B-thiolactone as models are found to undergo a-cleavage to give the diradical and carbene as reactive intermediates.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 02 Feb 2010 11:54
Last Modified: 19 Sep 2010 05:32
URI: http://eprints.iisc.ernet.in/id/eprint/20370

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