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Lanthanide perchlorate complexes of 4-nitroquinoline-1-oxide and 5-nitroisoquinoline-2-oxide

Kalyanasundaram, R and Navaneetham, NS and Soundararajan, S (1985) Lanthanide perchlorate complexes of 4-nitroquinoline-1-oxide and 5-nitroisoquinoline-2-oxide. In: Monatshefte für Chemie / Chemical Monthly, 116 (8-9). pp. 913-919.

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Abstract

Novel complexes of lanthanide perchlorates with 4-nitroquinoline-1-oxide (NQNO) and 5-nitroisoquinoline-2-oxide (NIQNO) have been prepared and characterized. The complexes have the general formulaeLn(NQNO)8(ClO4)3 (whereLn=La-Nd), Ln(NQNO)7(ClO4)3 (whereLn=Gd-Yb),Ln(NIQNO)9(ClO4)3 (whereLn=La-Nd), andLn(NIQNO)7(ClO4)3 (whereLn=Gd-Yb). The IR, proton NMR spectral data indicate the coordination of the N—O group of the ligands to he lanthanide ions.

Item Type: Journal Article
Additional Information: The copyright of this article belongs to Springer.
Keywords: 4-Nitroquinoline-1-oxide - 5-Nitroisoquinoline-2-oxide - Lanthanide perchlorates hypersensitive bands.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 27 Aug 2009 07:12
Last Modified: 19 Sep 2010 05:32
URI: http://eprints.iisc.ernet.in/id/eprint/20405

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