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The dipole moments and molecular structure of substituted acetamides

Soundararajan, Sundaresa (1957) The dipole moments and molecular structure of substituted acetamides. In: Transactions of the faraday society, 53 (2). pp. 159-166.

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Thioacetamide has a dipole moment substantially higher than the vector sum of the normal characteristic moments of its constituent bonds. However, the effect can reasonably be accounted for on the scheme of alterations in charge distribution and hence of bond moments proposed by Smith, Ree, Magee and Eyring. The same is probably true for chloroacetamide even though the problem of rotation about the C-C single bond renders the conclusion less certain. For cyanoacetamide, the observed moment cannot be accounted for satisfactorily on this basis.

Item Type: Journal Article
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Additional Information: Copyright for this article belongs to Royal Society of Chemistry.
Department/Centre: Others
Date Deposited: 30 May 2009 18:45
Last Modified: 19 Sep 2010 05:33
URI: http://eprints.iisc.ernet.in/id/eprint/20515

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