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Mean-field results of a lattice-gas model of multilayer adsorption

Yashonath, S and Sarma, DD (1984) Mean-field results of a lattice-gas model of multilayer adsorption. In: Chemical Physics Letters, 110 (3). pp. 265-269.

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Abstract

A lattice-gas model of multilayer adsorption has been solved in the mean-field approximation by a different numerical method. Earlier workers obtained a single solution for all values of temperature and pressure. In the present work, multiple solutions have been obtained in certain regions of temperature and pressure which give rise to bysteresis in the adsorption isotherm. In addition, we have obtained a parameter which behaves like an order parameter for the transition. The potential-energy function shows a double minimum in the region of bysteresis and a single maximum elsewhere.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 04 Feb 2010 07:00
Last Modified: 19 Sep 2010 05:33
URI: http://eprints.iisc.ernet.in/id/eprint/20638

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