HNbWO6 and HTaWO6: Novel oxides related to ReO3 formed by ion exchange of rutile-type LiNbWO6 and LiTaWO6

Bhat, Vasudeva and Gopalakrishnan, J (1986) HNbWO6 and HTaWO6: Novel oxides related to ReO3 formed by ion exchange of rutile-type LiNbWO6 and LiTaWO6. In: Journal of Solid State Chemistry, 63 (2). pp. 278-283.

PDF http___www.sciencedirect.com_science__ob=MImg&_imagekey=B6WM2-4B6NW23-BT-7&_cdi=6922&_user=512776&_orig=search&_coverDate=07_01_1986&_sk=999369997&view=c&wchp=dGLbVtb-zSkzS&md5=b8f632b81f00.pdf - Published Version Restricted to Registered users only Download (400Kb) | Request a copy

Abstract

Both LiNbWO6 and LiTaWO6 undergo ion exchange in hot aqueous H2SO4 yielding the hydrates HMWO6 · H2O (M = Nb or Ta). The reaction is accompanied by a structural transformation from the rutile to the ReO3 structure. The cell constants are a = 3.783(3)Å for HNbWO6 · H2O and a = 3.785(5)Å for HTaWO6 · H2O. The ReO3 structure is retained by the dehydration products HMWO6 and MWO5.5 as well. HMWO6 phases yield H1+xMWO6 hydrogen bronzes on exposure to hydrogen in the presence of platinum catalyst.

Item Type:	Journal Article
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	12 Aug 2009 08:27
Last Modified:	19 Sep 2010 05:36
URI:	http://eprints.iisc.ernet.in/id/eprint/21243

Actions (login required)

View Item