Manthiram, A and Sarode, PR and Madhusudan, WH and Gopalakrishnan, J and Rao, CNR (1980) X-ray spectroscopic study of chromium, nickel, and molybdenum compounds. In: Journal of Physical Chemistry, 84 (17). pp. 2200-2203.
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Chemical shifts in the K-absorption edges, AE, of a series of chromium, nickel, and molybdenum compounds have been investigated. The AE values in a given series vary in the same direction as the metal-core-level binding energies obtained from X-ray photoelectron spectroscopy. The AI3 values are related to the effective atomic charge of the metal by a parabolic relation. In the case of molybdenum compounds, the chemical shifts of the K, emission lines vary in the same manner as M.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to ACS Publications.|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||29 Jan 2010 08:04|
|Last Modified:||19 Sep 2010 05:36|
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