Sreekanth, CS and Hegde, MS and Rao, CNR (1987) An ultraviolet photoelectron spectroscopic study of the electron states of iodine complexes with electron donors. In: Spectrochimica Acta Part A: Molecular Spectroscopy, 43 (4). pp. 471-473.
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HeI photoelectron spectra of the vapour phase complexes of diethylether and diethylsulphide with iodine have been investigated for the first time. The iodine orbital ionization energy decreases on complexation while the donor lone-pair orbital ionization energy increases markedly; the shifts are considerably larger in the sulphide complex as expected on the basis of enthalpy considerations.
|Item Type:||Journal Article|
|Additional Information:||Copy right of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||07 Jan 2010 06:57|
|Last Modified:||19 Sep 2010 05:37|
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