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An elegant direct route for the preparation of pyridinium, ammonium and alkali metal hexafluorotitanates (IV)

Mohamed, Syed K and Padma, Doddaballapur K (1987) An elegant direct route for the preparation of pyridinium, ammonium and alkali metal hexafluorotitanates (IV). In: Journal of Fluorine Chemistry, 35 (2). pp. 411-414.

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Abstract

Pyridinium hexafluorotitanate (IV) has been prepared by a one step procedure. Addition of titanium tetrachloride to pyridinium poly(hydrogen fluoride) yields nearly quantitative amounts of pyridinium hexafluorotitanate(IV). Making use of pyridinium hexafluorotitanate as precursor, ammonium and alkali metal (Na, K, Rb, and Cs) hexafluorotitanates have been prepared in good yields. These salts have been characterised by IR, N.M.R. (1H, 13C and 19F), X-ray powder diffraction data and chemical analysis.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 15 Jul 2009 08:53
Last Modified: 19 Sep 2010 05:37
URI: http://eprints.iisc.ernet.in/id/eprint/21507

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