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A study in Crystal engineering: Solid-state photodimerization of chloro- and methyl-coumarins

Gnanaguru, K. and Murthy, GS and Venkatesan, K and Ramamurthy, V (1984) A study in Crystal engineering: Solid-state photodimerization of chloro- and methyl-coumarins. In: Chemical Physics Letters, 109 (3). pp. 255-258.

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Abstract

Use of chloro and methyl substitution in crystal engineering and their interchangeability in terms of mode of packing have been examined in a series of substituted coumarins. Photoreactivity in the solid state lists been correlated with the crystallograhic structures of these coumarins. The packing of chloro-substituted aromatic compounds has been investigated by analysing the arrangement of 132 compounds. Results substantiate the use of the chloro group as a steering agent and show that the chloro and methyl groups are not always interchangeable.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Feb 2010 12:14
Last Modified: 19 Sep 2010 05:38
URI: http://eprints.iisc.ernet.in/id/eprint/21579

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