Chandrashekar, TK and Krishnan, V (1981) Coordinative interaction of morpholine with divalent metallo tetraphenyl porphyrins. In: Journal of Inorganic and Nuclear Chemistry, 43 (12). pp. 3287-3290.
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The formation of axially coordinated morpholine (morph) complexes of MTPP, (M = Co, Ni, Cu and Zn) has been studied. Morpholine coordinates through imino nitrogen to the metal ions with the retainment of equatorial conformation. The presence of spin-free, NiTPP (morph), (S = 1) and an equilibrium mixture of CoTPP and an oxygen adduct of CoTPP (morph) in solution have been observed.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||22 Jul 2009 06:38|
|Last Modified:||19 Sep 2010 05:38|
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