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Structural Changes Accompanying the Formation of Isopentane Glass

Yashonath, S and Rao, CNR (1986) Structural Changes Accompanying the Formation of Isopentane Glass. In: Journal of Physical Chemistry, 90 (12). 2581 -2584.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/j100403a008

Abstract

On the basis of a detailed Monte Carlo study, it is found that considerable molecular reorientation occurs on the formation of the glassy state of isopentane. The reorientational contribution to the increase in the intermolecular energy on vitrification is at least 50% and reorientational freezing plays a major role near the glass transition. Annealing affects the structure of the glass by a rearrangement involving molecular reorientation.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 01 Feb 2010 10:22
Last Modified: 19 Sep 2010 05:39
URI: http://eprints.iisc.ernet.in/id/eprint/21813

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