Sumathi, K and Chandra, AK (1988) A comparative study of the photochemical hydrogen-abstraction reactions of a ketone and a thione. In: Journal of Photochemistry and Photobiology A: Chemistry, 43 (3). pp. 313-327.
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A perturbation treatment was developed for the comparative study of the abstraction of hydrogen from methane by formaldehyde and thioformaldehyde in their nπ* and ππ* states. Both in-plane and perpendicularplane reactions are considered. Results are qualitative but reveal clearly the prominent distinguishing features of these two photochemical processes in agreement with the experimental observations.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||04 Aug 2009 03:17|
|Last Modified:||19 Sep 2010 05:39|
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