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Synthesis and characterization of a rare hemiacetalate bridged incomplete View the MathML source dicubane cluster

Mondal, Kartik Chandra and Sengupta, Oindrila and Mukherjee, Partha Sarathi (2009) Synthesis and characterization of a rare hemiacetalate bridged incomplete View the MathML source dicubane cluster. In: Inorganic Chemistry Communications, 12 (7). pp. 682-685.

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Abstract

Reaction of 2-pyridinecarboxaldehyde [(Py)CHO] with Cu(NO3)2·2.5H2O in the presence of 4-aminopyridine and NaN3 in MeOH lead to an incomplete double-cubane [Cu4{PyCH(O)(OMe)}4(N3)4] (1) in 87% isolated yield, representing a rare type of metal cluster containing bridging hemiacetalate ligand [pyCH(O)(OMe)]−1 which was characterized by single crystal structure analysis and variable temperature magnetic behavior.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Antiferromagnetic;Crystal structure;Azide;Copper(II).
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 22 Dec 2009 09:18
Last Modified: 19 Sep 2010 05:42
URI: http://eprints.iisc.ernet.in/id/eprint/22454

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