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Synthesis of Thioesters from Carboxylic Acids via Acyloxyphosphonium Intermediates with Benzyltriethylammonium Tetrathiomolybdate as the Sulfur Transfer Reagent

Gopinath, Purushothaman and Vidyarini, Ravindran Sasitha and Chandrasekaran, Srinivasan (2009) Synthesis of Thioesters from Carboxylic Acids via Acyloxyphosphonium Intermediates with Benzyltriethylammonium Tetrathiomolybdate as the Sulfur Transfer Reagent. In: Journal of Organic Chemistry, 74 (16). pp. 6291-6294.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo9009694

Abstract

An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Keywords: Chemical ligation;organic-synthesis;carbon-carbon;s-alkyl;thiolesters; disulfides;conversion;chemistry;proteins; peptide.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 21 Dec 2009 08:54
Last Modified: 19 Sep 2010 05:43
URI: http://eprints.iisc.ernet.in/id/eprint/22737

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