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Photolysis of the dithiolactone 4-isopropylidene-3,3-dimethyl-1-thietan-2-thione; a Norrish type I reaction

Muthuramu, K and Ramamurthy, V (1980) Photolysis of the dithiolactone 4-isopropylidene-3,3-dimethyl-1-thietan-2-thione; a Norrish type I reaction. In: Journal of the Chemical Society, Chemical Communications (5). pp. 243-244.

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Abstract

The dithiolactone (1) upon excitation gives the dithione (2) in cyclohexane and other aprotic solvents and a 1 : 1 adduct in hydroxylic solvents from an n* excited singlet state via an -cleavage process.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry, 2009
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 08 Feb 2010 12:19
Last Modified: 19 Sep 2010 05:43
URI: http://eprints.iisc.ernet.in/id/eprint/22924

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