Bandekar, Jagdeesh (1973) Intensity of a Raman Overtone Band. In: Spectroscopy Letters, 6 (11). 675- 679.Full text not available from this repository. (Request a copy)
Placzek  was the first to derive general expressions for the intensities of overtones in case of Raman scattering. He assumed electrical anharmonicity. However, he left the expressions for the derivations of the polarizability tensor undetermined. In 1941, a classical and semiempirical theory was developed by Wolkenstein . He assumed the validity of the additivity of bond polarizabilities. However, the expressions derived by him for the intensities of overtones remain yet to be verified. It is the purpose of this paper to derive a formula for Raman polarizability tensor for overtones of (intramolecular) vibrational spectra along the lines of Kondilenko et al. [3,4].
|Item Type:||Journal Article|
|Additional Information:||Copy right of this article belongs to Taylor and Francis Group.|
|Department/Centre:||Division of Biological Sciences > Molecular Biophysics Unit|
|Date Deposited:||07 Jan 2010 05:30|
|Last Modified:||07 Jan 2010 05:30|
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