Manthiram, A and Gopalakrishnan, Jagannatha (1980) New A2+Mo4+O3 oxides with defect spinel structure. In: Materials Research Bulletin, 15 (2). pp. 207-211.
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New A2+Mo4+O3 oxides for A = Mn, Co and Zn crystallizing in a defect spinel structure have been prepared by hydrogen-reduction of the corresponding AMoO4 oxides. X-ray powder diffraction intensity analysis of the zinc compound indicates that the cation distribution is (Zn)t[Zn1/3Mo4/3□1/3]oO4. The defect spinels are metastable decomposing to a mixture of A2Mo3O8 and AO at high temperatures. Electrical and magnetic properties of the spinel phases are reported.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier science, 2009|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||21 Jan 2010 07:12|
|Last Modified:||19 Sep 2010 05:44|
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