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Iron(II, III) complexes with N, N'-DI(2-)Pyridyl Thiourea. Moumlssbauer and other spectroscopic studies

Sathyanarayana, DN and Burman, Sudhir (1982) Iron(II, III) complexes with N, N'-DI(2-)Pyridyl Thiourea. Moumlssbauer and other spectroscopic studies. In: Journal of Coordination Chemistry, 11 (4). pp. 219-223.

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Abstract

Several iron(II, III) complexes of N, N'-di(2-)pyridyl thiourea have been synthesized. The preparation of the complexes from iron(III) salts proceeds through a reduction of iron(III) to iron(II) followed by a subsequent reoxidation. The Moumlssbauer, electronic and infrared spectra of these complexes have been measured. The results are concordant with the coordination of pyridine nitrogens and thiocarbonyl sulfur yielding polymeric complexes. A variable temperature NMR study of the free ligand shows that two conformation are accessible for it in solution at subambient temperatures.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and Francis Group
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 22 Dec 2009 09:05
Last Modified: 22 Dec 2009 09:05
URI: http://eprints.iisc.ernet.in/id/eprint/23130

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