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Rates of oxidation of thioketones by singlet oxygen

Ramesh, V and Ramnath, N and Rao, V Jayathertha and Ramamurthy, V (1982) Rates of oxidation of thioketones by singlet oxygen. In: Journal of Photochemistry, 18 (2). pp. 109-115.

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Abstract

Rate constants for the quenching of singlet oxygen by a series of thioketones were measured by monitoring the inhibition of the self-sensitized photooxidation of rubrene. A correlation of the quenching rate with the nature of the substituents on the aromatic rings for the diarylthioketones and arylalkylthioketones was found, whereas correlation with the n orbital ionization potential was observed for the dialkylthioketones.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Publisher.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 22 Dec 2009 07:17
Last Modified: 19 Sep 2010 05:45
URI: http://eprints.iisc.ernet.in/id/eprint/23202

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