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Gas-Solid Reactions: Photochemical Oxidation of Thioketones in the Crystalline State

Arjunan, P and Ramamurthy, V and Venkatesan, K (1984) Gas-Solid Reactions: Photochemical Oxidation of Thioketones in the Crystalline State. In: Journal of Organic Chemistry, 49 (10). pp. 1765-1769.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo00184a019

Abstract

Photochemical oxidation of 11 diaryl thioketones (1-11) was conducted in the solid state. Quite interestingly, of these only six were oxidized to the corresponding carbonyl compound whereas the rest were photostable. However, in solution all were readily oxidized. The difference in behavior between the thioketones in the solid state has been rationalized on the basis of molecular arrangement in the crystal. X-ray crystal structure analyses of four thioketones were carried out in this connection.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 20 Jan 2010 09:40
Last Modified: 19 Sep 2010 05:45
URI: http://eprints.iisc.ernet.in/id/eprint/23414

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