Rangaraja, SK and Sangaranarayanan, MV (1980) Microscopic modelling of adsorption and the generalised surface layer hypothesis. In: Canadian Journal Of Chemistry-Revue Canadienne De Chimie, 59 (13). pp. 2072-2079.
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Two- and three-state models for the adsorption of organic compounds at the electrodelelectrolyte interface are proposed. Different size requirements, if any, for the neutral molecule and the adsorbing solvent are also considered. It is shown how the empirical, generalised surface layer (GSL) relationship (between the potential difference and the electrode charge) formulated by Damaskin et a / . can be understood at the molecular level.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to NRC Research Press.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||11 Jan 2010 12:18|
|Last Modified:||19 Sep 2010 05:46|
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