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2,6-Lutidine-N-oxide complexes of rare-earth bromides

Sivapullaiah, PV and Soundararajan, S (1981) 2,6-Lutidine-N-oxide complexes of rare-earth bromides. In: Journal of Chemical Sciences, 90 (2). pp. 131-135.

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Abstract

2,6-Lutidine-N-oxide (LNO) complexes of rare-earth bromides of the composition $$MBr_3 .(LNO)_{4_{ - n} } .nH_2 O$$ wheren = l for M = La, Pr, Nd, Sm, Gd, Ho, Er; andn = 0 for M = Y have been prepared and characterised by analyses, conductance and infrared data. Infrared spectra of the complexes indicate that the coordination of ligand to the metal ion takes place through the oxygen of the ligand, and the water molecule in the complexes present is coordinated to the metal. A coordination number of seven has been suggested to all the rare-earth metal ions.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Springer India,
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 01 Oct 2009 11:40
Last Modified: 03 Aug 2011 10:31
URI: http://eprints.iisc.ernet.in/id/eprint/23743

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