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Complexes of lanthanide iodides with 3-methylpyridine-1-oxide

Ramakrishnan, Lakshminarayanan and Sundararajan, Sundaresa (1976) Complexes of lanthanide iodides with 3-methylpyridine-1-oxide. In: Canadian Journal of Chemistry, 54 (20). pp. 3169-3174.

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Abstract

Complexes of lanthanide iodides with 3-methylpyridine-1-oxide of the formula Ln(3-MePyO)8I3.xH2O where x = 0 for Ln = La and Tb, x = 1 for Ln = Pr, and x = 2 for Ln = Nd, Sm, Dy, Yb, and Y have been prepared and characterized by chemical analyses, conductance, infrared, proton nmr, and DTA data. Infrared and proton nmr data have been interpreted in terms of the coordination of the ligand to the metal ion through the oxygen of the N—O group. Proton nmr spectrum of the Yb(III) complex is indicative of a restricted rotation of the pyridine ring about the N—O bond.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to NRC Canada.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 11 Dec 2009 09:17
Last Modified: 19 Sep 2010 05:48
URI: http://eprints.iisc.ernet.in/id/eprint/23942

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